public static void CheckFileType() { string path = @"D:\word.doc"; System.IO.FileStream fs = new System.IO.FileStream(path, System.IO.FileMode.Open, System.IO.FileAccess.Read); System.IO.BinaryReader r = new System.IO.BinaryReader(fs); string bx = " "; byte buffer; try { buffer = r.ReadByte(); bx = buffer.ToString(); buffer = r.ReadByte(); bx += buffer.ToString(); } catch (Exception exc) { Console.WriteLine(exc.Message); } r.Close(); fs.Close(); //真實的文件類型 Console.WriteLine(bx); //文件格式 Console.WriteLine(System.IO.Path.GetExtension(path)); Console.ReadLine(); } public enum FileExtension { JPG = 255216, GIF = 7173, BMP = 6677, PNG = 13780, COM = 7790, EXE = 7790, DLL = 7790, RAR = 8297, ZIP = 8075, XML = 6063, HTML = 6033, ASPX = 239187, CS = 117115, JS = 119105, TXT = 210187, SQL = 255254, BAT = 64101, BTSEED = 10056, RDP = 255254, PSD = 5666, PDF = 3780, CHM = 7384, LOG = 70105, REG = 8269, HLP = 6395, DOC = 208207, XLS = 208207, DOCX = 208207, XLSX = 208207, } 調用實例:string txt= CheckFileType(); if(txt=="")